Heh... this is fun.
So a quick list of people who could become super heros would be:
1. Bill Gates
2. Steve Ballmer
3. Steve Jobs
4. Larry Ellison
5. Paul Allen
6. Steve Wozniak
Ofcourse for every hero, you need five or six villians. From the top list, I would put Steve Wozniak as most likely to be a hero. And the rest would be the super villians that Wozman would fight! :)